Complexes of germanium(iv) fluoride with phosphane ligands: structural and spectroscopic authentication of germanium(iv) phosphane complexes

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Complexes of germanium(IV) fluoride with phosphane ligands: structural and spectroscopic authentication of germanium(IV) phosphane complexes.

The first phosphane complexes of germanium(iv) fluoride, trans-[GeF(4)(PR(3))(2)] (R = Me or Ph) and cis-[GeF(4)(diphosphane)] (diphosphane = R(2)P(CH(2))(2)PR(2), R = Me, Et, Ph or Cy; o-C(6)H(4)(PR(2))(2), R = Me or Ph) have been prepared from [GeF(4)(MeCN)(2)] and the ligands in dry CH(2)Cl(2) and characterised by microanalysis, IR, Raman, (1)H, (19)F{(1)H} and (31)P{(1)H} NMR spectroscopy. ...

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ژورنال

عنوان ژورنال: Dalton Transactions

سال: 2008

ISSN: 1477-9226,1477-9234

DOI: 10.1039/b716765b